Г. Эффективные атомные радиусы

Размеры атома или иона определяются его электронной оболочкой. Однако оболочка не ограничена определённой поверхностью, поэтому эффективный радиус атома задаётся вандерваальсовым радиусом. Этот радиус определяется на основании наименьшего энергетически выгодного расстояния между двумя атомами, не связанными ковалентной связью. На таком расстоянии энергия взаимодействия, определяемая силами притяжения и отталкивания, достигает минимального значения. Это расстояние соответствует сумме вандерваальсовых радиусов двух атомов. Форма и величина молекул в наиболее наглядном виде демонстрируется с помощью вандерваальсовой модели, где каждый атом занимает часть (сегмент) сферы соответствующего радиуса.


Основы биохимии. Общая химия / Строение молекул

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